Organic Chemistry Structure and Reactivity

A practical introduction to orbital interaction theory and its applications in modern organic chemistry Orbital interaction theory is a conceptual construct that lies at the very heart of modern organic chemistry. Comprising a comprehensive set of principles for explaining chemical reactivity, orbital interaction theory originates in a rigorous theory of electronic structure that also provides the basis for the powerful computational models and techniques with which chemists seek to describe and exploit the structures and thermodynamic and kinetic stabilities of molecules. Orbital Interaction Theory of Organic Chemistry, Second Edition introduces students to the fascinating world of organic chemistry at the mechanistic level with a thoroughly self-contained, well-integrated exposition of orbital interaction theory and its applications in modern organic chemistry. Professor Rauk reviews the concepts of symmetry and orbital theory, and explains reactivity in common functional groups and reactive intermediates in terms of orbital interaction theory. Aided by numerous examples and worked problems, he guides readers through basic chemistry concepts, such as acid and base strength, nucleophilicity, electrophilicity, and thermal stability (in terms of orbital interactions), and describes various computational models for describing those interactions. Updated and expanded, this latest edition of Orbital Interaction Theory of Organic Chemistry includes a completely new chapter on organometallics, increased coverage of density functional theory, many new application examples, and worked problems. The text is complemented by an interactive computer program that displays orbitals graphically and isavailable through a link to a Web site. Orbital Interaction Theory of Organic Chemistry, Second Edition is an excellent text for advanced-level undergraduate and graduate students in organic chemistry.

Traditionally, physical organic chemistry and theoretical organic chemistry have been treated as separate disciplines. This new book bridges these two areas in order to give the reader a new perspective on the nature of organic reactivity. A key element of this new approach is the author's extensive nonmathematical description of the recently developed curve-crossing model that describes why chemical reactions have an activation barrier, and specifies the factors that govern the barrier heights. In addition, the author draws from physical chemistry and transition-metal chemistry to present an original and detailed description of electron transfer theory, and covers the recent discovery that the electron transfer process is intimately related to many basic organic processes. This book has been divided into three parts to facilitate its mixture of classical organic chemistry with new and established theoretical ideas. Part A presents an introductory description of molecular orbital and valence bond theories with emphasis on the qualitative aspects that can be applied to practical problems in organic structure and reactivity. Part B describes the key principles of physical organic chemistry and incorporates a mainly qualitative description of the Marcus theory of electron transfer. Building on the theoretical framework developed in parts A and B, part C offers an overview of the basic reactions of organic chemistry: nucleophilic and electrophilic substitution, and radical and pericyclic reactivity. In addition, part C clearly explains the most recent unifying description of organic reactivity for organic chemists and for graduate and advanced undergraduate students.

Organic chemistry - Organic chemistry is the scientific study of the structure, properties, composition, reactions, and synthesis of organic compounds that by definition contain carbon. It is a specific discipline within the subject of chemistry.

Organic and Biomolecular Chemistry - Organic and Biomolecular Chemistry is a scientific journal devoted to Organic chemistry published since 2003 by the Royal Society of Chemistry. Its predecessor journals were Perkin Transactions I and Perkin Transactions II.

IUPAC nomenclature of organic chemistry - The IUPAC nomenclature of organic chemistry is a systematic way of naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Ideally, every organic compound should have a name from which an unambiguous structural formula can be drawn.

List of organic chemistry topics - This is a list of organic chemistry topics. This page should serve as the starting point for a well-balanced understanding of organic chemistry.

organicchemistrystructureandreactivity

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